Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Compounds of three types, [LnL3(C2H5OH)] (Ln = Nd (I), Sm (II), Eu (III)), [LnL3(H2O)] (Ln = = Gd (IV), Tb (V)), and [DyL2(NO3)(C2H5OH)2] (VI), were obtained by reactions of lanthanide nitrate with NaL (L– = 2,4-dichlorophenoxyacetate anion) in ethanol. The composition and structure of complexes I–VI were investigated by elemental and thermogravimetric analysis, IR spectroscopy, and X-ray diffraction (nos. 2311578 (I), 2311579 (II), 2311580 (III) 2311581 (IV), 2311582 (VI)). All compounds have a one-dimensional polymer structure in which metal atoms are connected by bridging carboxylate groups. The π–π interactions and intermolecular contacts between the chains give rise to a three-dimensional supramolecular structure.

Texto integral

Acesso é fechado

Sobre autores

M. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shuvic@gmail.com
Rússia, Moscow

O. Konnik

Vernadsky Crimea Federal University

Email: shuvic@gmail.com
Rússia, Simferopol

V. Shulgin

Vernadsky Crimea Federal University

Autor responsável pela correspondência
Email: shuvic@gmail.com
Rússia, Simferopol

A. Gusev

Vernadsky Crimea Federal University

Email: shuvic@gmail.com
Rússia, Simferopol

Bibliografia

  1. Hou S.L., Dong J., Tang M.H. et al. // Anal. Chem. 2019. V. 91. P. 5455.
  2. Wen G.X., Wu Y.P., Dong W.W. et al. // Inorg. Chem. 2016. V. 55. P. 10114.
  3. Yan W., Wang L., Yangxiao K. et al. // Dalton Trans. 2016. V. 45. P. 4518.
  4. Wei J.H., Yi J.W., Han M.L. et al. // Chem. Asian J. 2020. V. 14. P. 3694.
  5. Zeng M.H., Yin Z., Tan Y.X. et al. // J. Am. Chem. Soc. 2014. V. 136. P. 4680.
  6. Zhou L.J., Deng W.H., Wang Y.L. et al. // Inorg. Chem. 2016. V. 55. P. 6271.
  7. Kim T.H., White A.R., Sirdaarta J.P. et al. // ACS Appl. Mater. Interfaces. 2016. V. 8. P. 33102.
  8. Chen D., Xu W., Zhou Y. et al. // J. Mater. Chem. C. 2017. V. 5. P. 738.
  9. Fan Y., Guo X., Zhang Y. et al. // ACS Appl. Mater. Interfaces. 2016. V. 8. P. 31863.
  10. Ji W.-Q., Zhang Q.-H., Wang C.-F. et al. // Ind. Eng. Chem. Res. 2016. V. 55. P. 11700.
  11. Shang M., Li C., Lin J. // Chem. Soc. Rev. 2014. V. 43. P. 1372.
  12. Zhao D., Rao X., Yu J. et al. // Inorg. Chem. 2015. V. 54. P. 11193.
  13. Andres J., Hersch R.D., Moser J.-E. et al. // Adv. Funct. Mater. 2014. V. 24. P. 5029.
  14. De Bastiani M., Saidaminov M., Dursun I. et al. // Chem. Mater. 2017. V. 29, P. 3367.
  15. Lin J., Lai M., Dou L. et al. // Nat. Mater. 2018. V. 17. P. 261.
  16. Kang X.M., Hu H.S., Wu Z.L. et al. // Angew. Chem., Int. Ed. 2019. V. 58. P. 16610.
  17. D´Andrade B.W., Forrest S.R. // Adv. Mater. 2004. V. 16. P. 1585.
  18. Ouchi A., Suzuki Y., Ohki Y., Koizumi Y. // Coord. Chem. Rev. 1988. V. 92. P. 29.
  19. Smith G., Kennard C.H.L., White A.H. // J. Chem. Soc. Perkin Trans. 2. 1976. № 7. P. 791.
  20. Dendrinou-Samara C., Drosou D., Iordanidis L. et al. // J. Inorg. Biochem. 2002. V. 92. P. 156.
  21. Guo J., Liang W.J., Song W.D. // Acta Crystallogr. E. 2007. V. 63. P. 1595.
  22. Shi S.M., Chen Z.F., Liu L. // J. Coord. Chem. 2008. V. 61. P. 2725.
  23. Ma D., Qin L., Zhao H. et al. // Synthetic Metals. 2012. V. 162. P. 2282.
  24. Ma D., Lu K., Guo H. et al. // J. Mol. Struct. 2012. V. 1021. P. 179.
  25. Gusev A.N., Konnik O.V., Shul´gin V.F et al. // Polyhedrone. 2023. 116749.
  26. SMART (control) and SAINT (integration) Sofware. Version 5.0. Madison (WI, USA): Bruker AXS Inc., 1997.
  27. Krause L., Herbst-Irmer R., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. P. 1907.
  28. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
  29. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2015. V. 42. P. 339.
  30. Ruiz-Martínez A., Casanova D., Alvarez S. // Chem. Eur. J. 2008. V. 14. P. 1291.
  31. Nakamoto K. Infrared and RamanSpectra of Inorganic and Coordination Compounds. Pt A: Theory and Applicationsin Inorganic Chemistry. Hoboken (New Jersey): John Wiley & Sons, Inc., 2009. P. 183.

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2. Fig. 1. Centrosymmetric dimeric fragment of the polymer chain in III (different ways of coordination of carboxylate anion are shown)

Baixar (151KB)
Metadados
3. Fig. 2. Fragment of the polymer chain in IV (different ways of coordination of carboxylate anion are shown)

Baixar (179KB)
Metadados
4. Fig. 3. Fragment of the polymer chain in VI

Baixar (191KB)
Metadados
5. Fig. 4. Fragment of crystal packing II (carbon atoms of benzene rings bound by π...π- interactions are numbered)

Baixar (272KB)
Metadados
6. Fig. 5. Fragment of crystal packing IV (carbon atoms of benzene rings bound by π...π- interactions are numbered)

Baixar (298KB)
Metadados
7. Fig. 6. Fragment of crystal packing VI (carbon atoms of benzene rings bound by π...π- interactions are numbered)

Baixar (482KB)
Metadados

Declaração de direitos autorais © Российская академия наук, 2024