3-(2-Methylphenyl)-2-selenoxo-2,3-dihydroquinazolin-4(1H)-one and Its Complex with Cd(II): Synthesis and Molecular and Crystal Structures

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The reaction of methyl anthranilate with 2-methylphenyl-iso-selenocyanate in boiling absolute ethanol affords a new compound: 3-(2-methylphenyl)-2-selenoxo-2,3-dihydroquinazolin-4(1Н)-one (HL). Free ligand HL, which is selone, is preliminarily transformed into the corresponding sodium selenolate [C15H11N2OSeNa] (I), which is then used without isolation in the reaction with cadmium chloride. This reaction leads to the formation of complex [Cd2(μ-L)2(L)2(C2H5OH)2] (II). The structures of the compounds are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2142342 (НL) and 2246014 (II)) and NMR spectroscopy (1Н, 13С, 15N, and 77Se). In the crystal, the molecules of HL form one-dimensional chains due to H…O and H…Se contacts and alternate in the syndiotactic order. Compound II is the centrosymmetric binuclear complex [C64H56Cd2N8O6Se4]. The cadmium atoms in complex II are hexacoordinated by two chelate anionic ligands L–. According to the NMR data, in a DMSO-d6 solution free ligand HL has the selone structure, whereas in cadmium complex II this ligand exists in the selenolate form, which is consistent with the XRD data on the crystal structures of the compounds.

作者简介

R. Askerov

Baku State University

编辑信件的主要联系方式.
Email: rizvankam@bk.ru
阿塞拜疆, Baku

E. Chipinskii

Nizhni Novgorod State Technical University

Email: rizvankam@bk.ru
俄罗斯联邦, Nizhni Novgorod

A. Peregudov

Nesmeyanov Institute of Organic Element Compounds, Russian Academy of Sciences

Email: rizvankam@bk.ru
俄罗斯联邦, Moscow

V. Osmanov

Nizhni Novgorod State Technical University

Email: rizvankam@bk.ru
俄罗斯联邦, Nizhni Novgorod

Zh. Matsulevich

Nizhni Novgorod State Technical University

Email: rizvankam@bk.ru
俄罗斯联邦, Nizhni Novgorod

G. Borisova

Nizhni Novgorod State Technical University

Email: rizvankam@bk.ru
俄罗斯联邦, Nizhni Novgorod

V. Khrustalev

Peoples’ Friendship University of Russia; Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Email: rizvankam@bk.ru
俄罗斯联邦, Moscow; Moscow

O. Smirnova

National Research State University

Email: rizvankam@bk.ru
俄罗斯联邦, Nizhni Novgorod

A. Magerramov

Baku State University

Email: rizvankam@bk.ru
阿塞拜疆, Baku

A. Borisov

Nizhni Novgorod State Technical University

Email: rizvankam@bk.ru
俄罗斯联邦, Nizhni Novgorod

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