Ni-Al2O3-катализаторы пиролиза природного газа: зависимость физико-химических свойств и каталитической активности от температуры прокалки

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Abstract

Предложен способ синтеза Ni-Al2O3-катализаторов пиролиза природного газа, основанный на золь–гель-подходе с использованием псевдобёмита. Для синтезированного геля изучено влияние кальцинирования при различных температурах. Полученные материалы охарактеризованы методами низкотемпературной адсорбции азота, термопрограммируемого восстановления и рентгенофазового анализа. Изменение температуры прокалки приводит к изменению текстурных характеристик, кристалличности и степени взаимодействия активного компонента и носителя в результате чего катализаторы проявляют различную каталитическую активность. Наибольшую активность проявил образец, полученный при 650°C, что связано с повышенным объемом пор и степенью взаимодействия активной фазы и носителя.

About the authors

N. A. Vinogradov

Samara State Technical University

Samara, 443100 Russia

Yu. E. Galeeva

Samara State Technical University

Email: yulya.galeeva.01@mail.ru
Samara, 443100 Russia

V. I. Elizarova

Samara State Technical University

Samara, 443100 Russia

V. D. Dolgikh

Samara State Technical University

Samara, 443100 Russia

I. V. Kudinov

Samara State Technical University

Samara, 443100 Russia

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