Ni-Al2O3-катализаторы пиролиза природного газа: зависимость физико-химических свойств и каталитической активности от температуры прокалки

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Предложен способ синтеза Ni-Al2O3-катализаторов пиролиза природного газа, основанный на золь–гель-подходе с использованием псевдобёмита. Для синтезированного геля изучено влияние кальцинирования при различных температурах. Полученные материалы охарактеризованы методами низкотемпературной адсорбции азота, термопрограммируемого восстановления и рентгенофазового анализа. Изменение температуры прокалки приводит к изменению текстурных характеристик, кристалличности и степени взаимодействия активного компонента и носителя в результате чего катализаторы проявляют различную каталитическую активность. Наибольшую активность проявил образец, полученный при 650°C, что связано с повышенным объемом пор и степенью взаимодействия активной фазы и носителя.

作者简介

N. Vinogradov

Samara State Technical University

Samara, 443100 Russia

Yu. Galeeva

Samara State Technical University

Email: yulya.galeeva.01@mail.ru
Samara, 443100 Russia

V. Elizarova

Samara State Technical University

Samara, 443100 Russia

V. Dolgikh

Samara State Technical University

Samara, 443100 Russia

I. Kudinov

Samara State Technical University

Samara, 443100 Russia

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