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Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures
- Authors: Ivakhnenko E.P.1, Vitkovskaya Y.G.1, Merezhko N.I.1, Knyazev P.A.1, Borodkin G.S.1, Lysenko K.A.2, Minkin V.I.1
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Affiliations:
- Research Institute of Physical and Organic Chemistry, Southern Federal University
- Moscow State University
- Issue: Vol 50, No 4 (2024)
- Pages: 223-230
- Section: Articles
- URL: https://genescells.com/0132-344X/article/view/667603
- DOI: https://doi.org/10.31857/S0132344X24040017
- EDN: https://elibrary.ru/NQECRK
- ID: 667603
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Abstract
The Сd(II) complexes with redox amphoteric 2,6-di-(tret-butyl)-4-((2-hydroxyphenyl) imino)cyclohexa-2,5-dienone ligands L1 and L2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the 1Н, 13С, and 113Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.
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About the authors
E. P. Ivakhnenko
Research Institute of Physical and Organic Chemistry, Southern Federal University
Author for correspondence.
Email: ivakhnenko@sfedu.ru
Russian Federation, Rostov-on-Don
Yu. G. Vitkovskaya
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
Russian Federation, Rostov-on-Don
N. I. Merezhko
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
Russian Federation, Rostov-on-Don
P. A. Knyazev
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
Russian Federation, Rostov-on-Don
G. S. Borodkin
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
Russian Federation, Rostov-on-Don
K. A. Lysenko
Moscow State University
Email: ivakhnenko@sfedu.ru
Russian Federation, Moscow
V. I. Minkin
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
Russian Federation, Rostov-on-Don
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