The First Example of Dicubane Nickel(II) Complex in the Series of Unsymmetrically Substituted Diketones

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Resumo

The first homometal dicubane nickel(II) complex based on unsymmetrically substituted 1,3-diketone (1,1,1-trifluoro-4-(2-methoxyphenyl)butan-2,4-dione) was synthesized and studied by X-ray diffraction using synchrotron radiation (CCDC no. 861889). In the crystal of the complex, nickel atoms are joined into tetrahedra sharing a common vertex with Ni…Ni distances of 3.026–3.127 A; the geometry is completed to a distorted dicubane by μ3-bridging oxygen atoms of the hydroxyl groups. The coordination environment of each metal center is a distorted octahedron, the ligand is deprotonated and performs a bidentate function, forming six-membered chelate rings.

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Sobre autores

L. Khamidullina

Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B.N. Yeltsin

Email: puzyrev@ios.uran.ru
Rússia, Yekaterinburg; Yekaterinburg

I. Puzyrev

Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Autor responsável pela correspondência
Email: puzyrev@ios.uran.ru
Rússia, Yekaterinburg

P. Dorovatovsky

Kurchatov Institute

Email: puzyrev@ios.uran.ru
Rússia, Moscow

V. Khrustalev

Peoples' Friendship University of Russia; Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: puzyrev@ios.uran.ru
Rússia, Moscow; Moscow

A. Pestov

Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B.N. Yeltsin

Email: puzyrev@ios.uran.ru
Rússia, Yekaterinburg; Yekaterinburg

Bibliografia

  1. Shiga T., Newton G.N., Oshio H. // Dalton Trans. 2018. V. 47, № 22. P. 7384.
  2. Kirillov A.M., Kirillova M. V., Pombeiro A.J.L. // Coord. Chem. Rev. 2012. V. 256. № 23–24. P. 2741.
  3. Ungur L., Lin S.Y., Tang J. et al. // Chem. Soc. Rev. 2014. V. 43. № 20. P. 6894.
  4. Nesterov D.S., Nesterova O. V., Pombeiro A.J.L. // Coord. Chem. Rev. 2018. V. 355. P. 199.
  5. Wang K., Gao E. // Anticancer Agents Med. Chem. 2014. V. 14. № 1. P. 147.
  6. Muetterties E.L., Rhodin T.N., Band E. et al. // Chem. Rev. 1979. V. 79. № 2. P. 91.
  7. Zhao Q., Harris T.D., Betley T.A. // J. Am. Chem. Soc. 2011. V. 133. № 21. P. 8293.
  8. Sanz S., O´Connor H.M., Martí-Centelles V. et al. // Chem. Sci. 2017. V. 8. № 8. P. 5526.
  9. Horiuchi S., Tachibana Y., Yamashita M. et al. // Nat. Commun. 2015. V. 6. Art. 6742.
  10. Zaleski C.M., Tricard S., Depperman E.C., et al. // Inorg. Chem. 2011. V. 50. № 22. P. 11348.
  11. Engelhardt L.P., Muryn C.A., Pritchard R.G. et al. // Angew. Chem. Int. Ed. 2008. V. 47. № 5. P. 924.
  12. Schäfer B., Greisch J.F., Faus I. et al. // Angew. Chem.Int. Ed. 2016. V. 55. № 36. P. 10881.
  13. Shvachko Y.N., Starichenko D. V., Korolev A. V. et al. // Inorg. Chim. Acta. 2018. V. 483. P. 480.
  14. Murrie M., Stoeckli-Evans H., Güdel H.U. // Angew. Chem.. Int. Ed. 2001. V. 40, № 10. P. 1957.
  15. Aromí G., Parsons S., Wernsdorfer W. et al. // Chem. Commun. 2005. № 40. P. 5038.
  16. Keene T.D., Hursthouse M.B., Price D.J. // New. J. Chem. 2004. V. 32. № 9. P. 1.
  17. Petit S., Neugebauer P., Pilet G. et al. // Inorg. Chem. 2012. V. 51. № 12. P. 6645.
  18. Dong W.K., Zhu L.C., Dong Y.J. et al. // Polyhedron. 2016. V. 117. P. 148.
  19. Mameri S. // Inorg, Chim. Acta. 2017. V. 455. P. 231.
  20. Kuznetsova O. V., Fursova E.Y., Letyagin G.A. et al. // Russ. Chem. Bull. 2018. V. 67, № 7. P. 1202.
  21. Hameury S., Kayser L., Pattacini R. et al. // ChemPlusChem. 2015. V. 80 № 8. P. 1312.
  22. Khamidullina L.A., Puzyrev I.S., Glukhareva T. V. et al. // J. Mol. Struct. 2019. V. 1176. P. 515.
  23. Battye T.G.G., Kontogiannis L., Johnson O. et al. // Acta Crystallogr. D. 2011. V. 67, № 4. P. 271.
  24. Evans P. // Acta Crystallogr. D. 2006. V. 62. № 1. P. 72.
  25. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.

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2. Scheme 1

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3. Fig. 1. Molecular structure of complex I in thermal ellipsoids of 30% probability. Hydrogen atoms and the solvated water molecule are not depicted. For disordered groups only the major components are given

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4. Fig. 2. Structure of the inorganic core and coordination polyhedron of complex I according to PCA data

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5. Fig. 3. Coordination environment of the peripheral metal centre in complex I according to PCA data

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6. Fig. 1

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7. Fig. 2

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8. Fig. 3

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9. Fig. 4. FT-IR spectrum of complex I

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