Coordination compounds of uranyl nitrate with several amide ligands

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Resumo

Reactions of UO2(NO3)2 with an amide L (L = acetamide, N,N-dimethylacetamide, propanamide, valeramide, benzamide, N-methylurea) in aqueous media resulted in formation of 6 coordination compounds [UO2(L)2(NO3)2], their compositions and structures were determined by elemental analysis, IR-spectroscopy, RFA and X-ray diffraction. The molecular structure and assignment of absorption bands for the obtained compounds are confirmed by quantum-chemical calculations.

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Sobre autores

M. Polukhin

MIREA – Russian Technological University

Email: savinkina@mirea.ru

Lomonosov Institute of Fine Chemical Technologies

Rússia, Moscow

E. Savinkina

MIREA – Russian Technological University

Autor responsável pela correspondência
Email: savinkina@mirea.ru

Lomonosov Institute of Fine Chemical Technologies

Rússia, Moscow

I. Karavaev

MIREA – Russian Technological University

Email: savinkina@mirea.ru

Lomonosov Institute of Fine Chemical Technologies

Rússia, Moscow

P. Akulinin

MIREA – Russian Technological University

Email: savinkina@mirea.ru

Lomonosov Institute of Fine Chemical Technologies

Rússia, Moscow

G. Buzanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: savinkina@mirea.ru
Rússia, Moscow

A. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: savinkina@mirea.ru
Rússia, Moscow

M. Grigoriev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: savinkina@mirea.ru
Rússia, Moscow

S. Strashnova

RUDN University

Email: savinkina@mirea.ru

Faculty of Physics and Mathematics and Natural Sciences

Rússia, Moscow

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3. Fig. 1. Structure of compounds [UO2(L)2(NO3)2], where L = AA (a), PrA (b), MeUr (c) according to X-ray diffraction data.

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4. Fig. 2. Hydrogen bonds in structure I (a); fragment of the crystal packing of structure I (b).

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5. Fig. 3. Fragment of the crystal packing of structure III. The dotted lines show the intermolecular hydrogen bonds NH…O.

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6. Fig. 4. Hydrogen bonds in the structure of V.

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7. Fig. 5. Hydrogen bonds in structure VI.

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8. Fig. 6. Equilibrium geometries of compounds [UO2(L)2(NO3)2], where L = BzA (a), DMAA (b), VaA (c) according to quantum chemical calculations.

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