Synthesis and structures of mixed-ligand lead(II) complexes with decahydro-closo-decaborate anion and azheterocyclic ligands

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Lead(II) complexation reactions were studied in the presence of salts of the closo-decaborate anion [B10H10]2– and azaheterocyclic ligands 2,2΄-bipyridyl (bipy) or 1,10-phenanthroline (phen) in water and organic solvents (acetonitrile, DMF). Binuclear complex Pb(bipy)2[B10H10] and polymer complex [Pb(phen)[B10H10]] were isolated. The effect of solvents and reagent ratios on the composition and structures of the final complexes was studied. The complex compounds were identified by elemental analysis, IR spectroscopy, and X-ray powder diffraction. The structure of complex [Pb(bipy)2[B10H10]]2 ⋅ 2CH3CN (CCDC no. 2325841) was determined by single-crystal X-ray diffraction.

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V. Avdeeva

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: avdeeva.varvara@mail.ru
俄罗斯联邦, Moscow

A. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
俄罗斯联邦, Moscow

I. Kozerozhets

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
俄罗斯联邦, Moscow

S. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
俄罗斯联邦, Moscow

E. Malinina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
俄罗斯联邦, Moscow

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
俄罗斯联邦, Moscow

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2. Scheme 1: Synthesis of the compounds discussed in this work.

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3. Fig. 1. Structure of complex I - CH3CN: structure fragment (a), packing fragment (b).

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4. Fig. 2. dnorm-Hirschfeld surface of the [B10H10]2- anion in the structure of I (a); 2D-section of the Hirschfeld surface of the anion (b) and the contact boundaries of H...H (c), H...Pb (d) and H...N (e).

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5. Fig. 3. Theoretical X-ray diffraction of the complex [Pb(Bipy)[B10H10]] [26] (blue) and practical X-ray diagram of complex II (red).

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