Features of the changes in composition and structure of rare-earth halide complexes with acethylurea

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Abstract

Structures of rare-earth halide complexes with acetylurea (AcUr), [Sm(AcUr)2(H₂O)5]Cl3, [Eu(AcUr)2(H₂O)5]Br3 · · H₂O, [Ln(AcUr)2(H₂O)4]Br3 · H₂O (Ln = Tm, Yb), and [Lu(AcUr)(H₂O)6]Br3 were determined. Analysis of compositions and structures of these compounds along with the earlier reported analogues allowed us to consider the features of their changes depending on the atomic number of the element.It was found that the size of the central atom is the decisive factor.

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P. V. Akulinina

Lomonosov Institute of Fine Chemical Technologies, RTU MIREA

Email: savinkina@mirea.ru
Russian Federation, 86 Vernadsky, Moscow, 119571

E. V. Savinkina

Lomonosov Institute of Fine Chemical Technologies, RTU MIREA

Author for correspondence.
Email: savinkina@mirea.ru
Russian Federation, 86 Vernadsky, Moscow, 119571

M. S. Grigoriev

Frumkin Institute of Physical Chemistry and Electrochemistry, RAS

Email: savinkina@mirea.ru
Russian Federation, 31, Bldg 4 Leninsky pr., Moscow, 119071

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2. Fig. 1. Structure of the compound [Eu(AcUr)2(H2O)5]Br3 · H2O (I) at 100K according to X-ray diffraction data. Temperature shift ellipsoids are shown with a probability of 50%, hydrogen atoms are not shown.

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3. Fig. 2. Structure of the compound [Tm(AcUr)2(H2O)4]Br3 · H2O (II) at 100 K according to X-ray diffraction data. Temperature shift ellipsoids are shown with a probability of 50%, hydrogen atoms are not shown.

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4. Fig. 3. Structure of the compound [Lu(AcUr)(H2O)6]Br3 (IV) at 100 K according to X-ray diffraction data. Temperature shift ellipsoids are shown with a probability of 50%, hydrogen atoms are not shown.

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5. Fig. 4. General view of the starting geometry for connection II.

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