Synthesis and structure of cadmium, copper, and nickel pivalate and pentafluorobenzoate complexes with 2-amino-1-methylbenzimidazole

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

A series of copper(II), nickel(II), and cadmium(II) compounds with pivalate (Piv) or pentafluorobenzoate (Pfb) anions and 2-amino-1-methylbenzimidazole (L) molecules, [Cu2(Piv)4(L)2]·2MeCN (I), [Ni(Piv)2 (L)2][Ni(Piv)2(L)2(MeOH)] (II), and [Cd(Pfb)2(L)2] (III), were obtained. In the case of copper compounds, a binuclear complex with a Chinese lantern structure was formed, while nickel and cadmium salts gave mononuclear complexes. In all synthesized compounds, the 2-amino-1-methylbenzimidazole molecule is a monodentate ligand, being coordinated to the metal atom through the benzimidazole nitrogen atom. The compounds were characterized by X-ray diffraction, IR spectroscopy, and CHN analysis.

Толық мәтін

Рұқсат жабық

Авторлар туралы

A. Chistyakov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

M. Shmelev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: shmelevma@yandex.ru
Ресей, Moscow

L. Efromeev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: shmelevma@yandex.ru
Ресей, Moscow; Moscow

L. Popov

Southern Federal University

Email: shmelevma@yandex.ru
Ресей, Rostov-on-Don

Yu. Voronina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

A. Sidorov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

I. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

Әдебиет тізімі

  1. Ibrahim S.A., Ragab A., El-Ghamry H.A. // Appl. Organomet. Chem. 2021. V. 36. № 2. P. e6508.
  2. Psomas G. // Coord. Chem. Rev. 2020. V. 412. P. 213259.
  3. Abdel-Rahman L.H., Abdelhamid A.A., Abu-Dief A.M. et al. // J. Mol. Struct. 2020. V. 1200. P. 127034.
  4. Schwietert C.W., McCue J.P. // Coord. Chem. Rev. 1999. V. 184. № 1. P. 67.
  5. Krasnovskaya O., Naumov A., Guk D. et al. // Int. J. Mol. Sci. 2020. V. 21. № 11. P. 3965.
  6. Pellei M., Del Bello F., Porchia M., Santini C. // Coord. Chem. Rev. 2021. V. 445. P. 214088.
  7. Bansal Y., Silakari O. // Bioorg. Med. Chem. 2012. V. 20. № 21. P. 6208.
  8. Anastassova N., Aluani D., Hristova-Avakumova N. et al. // Antioxidants. 2022. V. 11. № 5. P. 884.
  9. Imran M., Ali Shah F., Nadeem H. // ACS Chem. Neurosci. 2021. V. 12. № 3. P. 489.
  10. Sterling J., Hayardeny L., Falb E. et al. // U.S. Pat. Appl. Publ., 2004, 25p.
  11. Law C.S.W., Yeong K.Y. // ChemMedChem. 2021. V. 16. № 12. P. 1861.
  12. Saylam M., Aydın Köse F., Pabuccuoglu A. et al. // Eur. J. Med. Chem. 2023. V. 248. P. 115083.
  13. Gaba M., Singh D., Singh S. et al. // Eur. J. Med. Chem. 2010. V. 45 № 6. P. 2245.
  14. Mohamed B.G., Abdel-Alim A.-A. M., Hussein M.A. // Acta Pharm. 2006. V. 56. P. 31.
  15. Soni B., Singh Ranawat M., Bhandari A. et al. // Pharmacie Globale (IJCP). 2012. V. 9 P. 05.
  16. Husain A., Varshney M.M., Rashid M. et al. // J. Pharm. Res. 2011. V. 4(2). P. 413.
  17. Coetzee J., Cronje S., Dobrzańska L. et al. // Dalton Trans. 2011. V. 40. P. 1471.
  18. Błaszczak-Świątkiewicz K., Olszewska P., Mikiciuk-Olasik E. // Pharmacol Rep. 2014. V. 66. P. 100.
  19. Shrivastava N., Naim J., Alam J. et al. // Arch. Pharm. 2017. V. 350. № 6. P. e201700040.
  20. Satija G., Sharma B., Madan A. et al. // J. Heterocycl. Chem. 2022. V. 59. № 1. P. 22.
  21. Shaker S.A., Khaledi H., Cheah S.-C., Mohd Ali H. // Arab. J. Chem. 2016. V. 9. № 2. P. S1943.
  22. Hernández-Romero D., Rosete-Luna S., López-Monteon A. et al. A. // Coord. Chem. Rev. 2021. V. 439. P. 213930.
  23. Шмелев М.А., Гоголева Н.В., Иванов В.К. и др. // Коорд. химия. 2022. Т. 48. № 9. С. 515 (Shmelev M.A., Gogoleva N.V., Ivanov V.K. et al. // Russ. J. Coord. Chem. 2022. V. 48. № 9. P. 539). https://doi.org/10.1134/S1070328422090056
  24. Voronina J.K, Yambulatov D.S., Chistyakov A.S. et al. // Crystals. 2023. V. 13. № 4. P. 678.
  25. Шмелев М.А., Гоголева Н.В., Кузнецова Г.Н. и др. // Коорд. химия. 2020. Т. 46 № 8. С. 497 (Shmelev M.A., Gogoleva N.V., Kuznetsova G.N. et al. // Russ. J. Coord. Chem. 2020. V. 46. № 8. P. 557). https://doi.org/10.1134/S1070328420080060
  26. Troyanov S. I., Il`ina E. G., Dunaeva K. M. // Russ. J. Coord. Chem. 1991. V. 17. P. 1692.
  27. Eremenko, I.L., Golubnichaya, M.A., Nefedov, S.E. et al. // Russ. Chem. Bull. 1998. V. 47. № 4. P. 704.
  28. SMART (control) and SAINT (integration). Software. Version 5.0. Madison (WI, USA): Bruker AXS Inc., 1997.
  29. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
  30. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339.
  31. Sheldrick G. Cell_Now. Madison (WI, USA): Bruker-AXS, Inc., 2004.
  32. Twinabs. Madison (WI, USA): Bruker AXS Inc., 2001.
  33. Casanova D., Llunell M., Alemany P., Alvarez S. et al. // Chem. Eur. J. 2005. V. 11. P. 1479.
  34. Denisova T.O., Aleksandrov G.G., Fialkovskii O.P., Nefedov S.E. // Russ. J. Inorg. Chem. 2003. V. 48. P. 1476.
  35. Morooka M., Ohba S., Nakashima M. et al. // Acta Crystallogr. C. 1992. V. 48. P. 1888.
  36. Kirillova N.I., Struchkov Yu.T., Porai-Koshits M.A. et al. // Inorg. Chim. Acta. 1980. V. 40. P. 115.
  37. Denisova T.O., Amel’chenkova E.V., Pruss I.V. et al. // Russ. J. Inorg. Chem. 2006. V. 51. P. 1098. https://doi.org/10.1134/S0036023606070084
  38. Eremenko I.L., Nefedov S.E., Sidorov A.A. et al. // Inorg. Chem. 1999. V. 38. P. 3764.
  39. Kounavi K.A., Manos M.J., Tasiopoulos A.J. et al. // Bioinorg. Chem. Appl. 2010. P. 178034.
  40. Shmelev M.A., Voronina J.K., Evtyukhin M.A. et al. // Inorganics. 2022. V. 10. P. 194.
  41. Gogoleva N.V., Shmelev M.A., Kiskin M.A. et al. // Russ. Chem. Bull. 2016. V. 65. P. 1198.
  42. Demaret A., Mercier D. // J. Appl. Crystallogr. 1983. V. 16. P. 279.
  43. Zhou Y.-H., Xu Y., Tao Q.-L. et al. // J. Inorg. Organomet. Polym. Mater. 2020. V. 30. P. 2376.
  44. Gao T., Dong B.-X., Sun Y. et al. // J. Mater. Sci. 2019. V. 54. P. 10644.
  45. Wang X., Xiao H. Zhang M. et al. // Polyhedron. 2020. V. 179. P. 114383.
  46. Daminova S.S., Kadirova Z.C., Sharipov K.T. et al. // J. Environ. Chem. Eng. 2020. V.10. P. 108900.
  47. Ozair L.N., Abdullah N., Khaledi H., Tiekink E.R.T. // Acta Crystallogr. E. 2010. V. 66. P. m589.
  48. Mikuriya M., Azuma H., Nukada R., Handa M. // Chem. Lett. 1999. V. 28. P. 57.
  49. Lada Z.G., Beobide A.S., Savvidou A. et al. // Dalton Trans. 2017. V. 46. P. 260.
  50. Rauf S., Trzesowska-Kruszynska A., Sieranski T., Swiatkowski M. // Molecules. 2021. V. 26. P. 3358.
  51. Bazhina E.S., Bovkunova A.A., Shmelev M.A. et al. // Polyhedron. 2022. V. 228. P. 116174.
  52. Yambulatov D.S., Nikolaevskii S.A., Lutsenko I.A. et al. // Russ. J. Coord. Chem. 2020. V. 46. P. 772. https://doi.org/10.1134/S1070328420110093
  53. Kuznetsova G.N., Nikolaevskii S.A., Yambulatov D.S. et al. // J. Struct. Chem. 2021. V. 62. P. 184.

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Әрекет
1. JATS XML
Жүктеу
2. Fig. 1. Structure of complex I. Solvate molecules are not shown.

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3. Fig. 2. Structure of compound II. Hydrogen bonds are shown by dotted lines.

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4. Fig. 3. Structure of complex III. Hydrogen atoms are not shown.

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5. Fig. 4. Fragment of the crystal packing of compound III. The dotted lines show hydrogen bonds and π–π interactions.

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6. Scheme 1. Synthesis of complexes I–III.

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