Synthesis and structure of cadmium, copper, and nickel pivalate and pentafluorobenzoate complexes with 2-amino-1-methylbenzimidazole

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Resumo

A series of copper(II), nickel(II), and cadmium(II) compounds with pivalate (Piv) or pentafluorobenzoate (Pfb) anions and 2-amino-1-methylbenzimidazole (L) molecules, [Cu2(Piv)4(L)2]·2MeCN (I), [Ni(Piv)2 (L)2][Ni(Piv)2(L)2(MeOH)] (II), and [Cd(Pfb)2(L)2] (III), were obtained. In the case of copper compounds, a binuclear complex with a Chinese lantern structure was formed, while nickel and cadmium salts gave mononuclear complexes. In all synthesized compounds, the 2-amino-1-methylbenzimidazole molecule is a monodentate ligand, being coordinated to the metal atom through the benzimidazole nitrogen atom. The compounds were characterized by X-ray diffraction, IR spectroscopy, and CHN analysis.

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Sobre autores

A. Chistyakov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Rússia, Moscow

M. Shmelev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: shmelevma@yandex.ru
Rússia, Moscow

L. Efromeev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: shmelevma@yandex.ru
Rússia, Moscow; Moscow

L. Popov

Southern Federal University

Email: shmelevma@yandex.ru
Rússia, Rostov-on-Don

Yu. Voronina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Rússia, Moscow

A. Sidorov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Rússia, Moscow

I. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shmelevma@yandex.ru
Rússia, Moscow

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2. Fig. 1. Structure of complex I. Solvate molecules are not shown.

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3. Fig. 2. Structure of compound II. Hydrogen bonds are shown by dotted lines.

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4. Fig. 3. Structure of complex III. Hydrogen atoms are not shown.

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5. Fig. 4. Fragment of the crystal packing of compound III. The dotted lines show hydrogen bonds and π–π interactions.

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6. Scheme 1. Synthesis of complexes I–III.

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